The Rare Examples of Thiosemicarbazonato Chromium(III) Complexes: Crystal Structures of [Cr(Hsal 4-Metsc)2]Cl CH3OH and [Cr(Hsal 4-Phtsc)2]Cl

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The Rare Examples of Thiosemicarbazonato Chromium(III) Complexes: Crystal Structures of [Cr(Hsal 4-Metsc)2]ClCH3OH and [Cr(Hsal 4-Phtsc)2]Cl

Reactions of salicylaldehyde 4-methylthiosemicarbazone (H2L) and salicylaldehyde 4phenylthiosemicarbazone (H2L) with assorted chromium(III) precusors, [Cr(H2O)6]Cl3, [Cr(H2O)6](NO3)33H2O and [Cr(H2O)6](CH3COO)3, afforded new mononuclear chromium(III) complexes of the general formula [Cr(HL)2]X (X = Cl, NO3 and CH3COO). In all isolated compounds, Cr(III) ion is coordinated by the O,N,S atoms of...

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ژورنال

عنوان ژورنال: Croatica Chemica Acta

سال: 2012

ISSN: 0011-1643,1334-417X

DOI: 10.5562/cca2153